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Brillouin Spectroscopy : ウィキペディア英語版 | Brillouin Spectroscopy
Brillouin spectroscopy is an empirical technique which allows for the determination of elastic moduli for a given material. The technique uses inelastic scattering of light when it encounters acoustic phonons in a crystal, a process known as Brillouin scattering, to determine phonon energies and therefore interatomic potentials of a material (Polian, 2003). The scattering occurs when an electromagnetic wave interacts with a density wave, photon-phonon scattering. This technique is commonly used in fields interested in the elastic properties of materials such as mineral physics and material science. Brillouin spectroscopy can be used to determine the complete elastic tensor of a given material which is required in order to understand the bulk elastic properties. ==Brillouin spectroscopy vs. Raman spectroscopy==
Brillouin spectroscopy is similar to Raman spectroscopy in many ways; in fact the physical scattering processes involved are identical. However, the type of information gained is significantly different. The process observed in Raman spectroscopy, Raman scattering, involves high frequency molecular rotational and vibrational modes. Information relating to modes of vibration, such as the six normal modes of vibration of the carbonate ion, (CO¬3)2-, can be obtained through a Raman spectroscopy study shedding light on structure and chemical composition (Buzgar, 2009), whereas Brillouin scattering involves the scattering of photons by low frequency phonons providing information regarding elastic properties (Bass, 1995). Optical phonons measured in Raman spectroscopy have wavenumbers on the order of 10–10000 cm¬-1, while phonons involved in Brillouin scattering are on the order of 0.1–6 cm-1. This order of magnitude difference becomes obvious when attempting to run Raman spectroscopy vs. Brillouin spectroscopy experiments. In Brillouin scattering, and similarly Raman scattering, both energy and momentum are conserved in the relations (Polian, 2003):
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